WebMechanism of the Upjohn Dihydroxylation. The toxic and volatile OsO 4 can also be prepared in situ by the oxidation of K 2 OsO 2 (OH) 4 with NMO. NMO is also the cooxidant that enables the use of a catalytic amount of OsO 4, because this reagent is able to reoxidize an Os(VI) species to an Os(VIII) species:. The mechanism is simplified, for example in … WebAn efficient and facile method for the synthesis of 3-indolyl-substituted phthalides by Friedel-Crafts alkylation of indoles with 3-hydroxyisobenzofuran-1(3H)-one has been developed. Using only 2 mol-% TsOH·H2O as the catalyst, various substituted indoles can react smoothly at room temperature to give the corresponding phthalides products in …
[PDF] TsOH·H2O-Catalyzed Friedel-Crafts of Indoles of 3 ...
Webp -Toluenesulfonic Acid Monohydrate. ・川口,尼崎倉庫の在庫は即日,その他の倉庫は2〜3営業日以内の出荷となります。. 川口,尼崎倉庫からの配送対象エリア は各々異なり … p-Toluenesulfonic acid (PTSA or pTsOH) or tosylic acid (TsOH) is an organic compound with the formula CH3C6H4SO3H. It is a white extremely hygroscopic solid that is soluble in water, alcohols, and other polar organic solvents. The CH3C6H4SO2 group is known as the tosyl group and is often abbreviated as Ts … See more TsOH is prepared on an industrial scale by the sulfonation of toluene. Common impurities include benzenesulfonic acid and sulfuric acid. TsOH monohydrate contains an amount of water. To estimate the total moisture … See more Alkyl tosylates are alkylating agents because tosylate is electron-withdrawing as well as a good leaving group. Tosylate is a pseudohalide. … See more • Tosyl • Collidinium p-toluenesulfonate See more • TsOH may be converted to p-toluenesulfonic anhydride by heating with phosphorus pentoxide. • When heated with acid and water, TsOH undergoes hydrolysis to toluene: CH3C6H4SO3H + … See more daiwa site officiel
p-Toluenesulfonic acid - Wikipedia
Webp-Toluene sulfonic acid (PTSA) or tosylic acid (TsOH) is an organic compound with the formula CH3C6H4SO3H. It is a white solid that is soluble in water, alcohols, and other … WebFeb 17, 2024 · General Description. p -Toluenesulfonic acid monohydrate, an oxonium salt, is an inexpensive and easy to handle organic catalyst used in organic synthesis. The study … WebA pyrrolopyrimidine or a pyrrolopyridine derivative and the medical use thereof. Specifically, the compound has a structure as represented by formula I. The compound has a good inhibitory effect on focal adhesion kinase (FAK) and inhibits a related signaling pathway thereof. The compound can be used in the preparation of a drug for preventing or treating … biotechnology podcast transcript